This paper investigates how electrolytic plasma hardening (PEH) bears upon the changes in the phase structural and tribological properties of steel 0.34C-1Cr-1Ni-1Mo-Fe, which is widely used in manufacturing highly stressed gears. The samples of steel 0.34C-1Cr-1Ni-1Mo-Fe went through the PEH in an electrolyte containing an aqua solution of 20% calcined soda (Na2CO3) and 10% carbamide ((NH2)2CO). The initial steel 0.34C-1Cr-1Ni-1Mo-Fe is stated to have the following structural components: a lamellar pearlite with volume share of 35%, a ferrite-carbide mixture of ~45% and a fragmented ferrite of ~20%; after the PEH it contains lath-lamellar martensite, fine particles of cementite and M23C6 carbide. The durability of steel 0.34C-1Cr-1Ni-1Mo-Fe was found to rise by 3.4 times after the PEH and its microhardness increased in 2.6 times. The curve-tension of the crystal lattice was established to be like plastic ( = pl) and does not cause the formation of microcracks in the material.
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